If you make a circle in paintDOTnet one pixel thick you get a blurred line, at is tried to spread the top, bottom and sides of the circle over 2 pixels not one...
The word is that this is hard to fix, in a previous post the suggestion was to make a 2 pixel with circle twice the desired size and shrink the image, but the result will still be fuzzy if you don't get the pixels aligned correctly both vertically and horizontally, this was an awkward horrible solution...
I had found that make the circle 2 pixels thick and using a white circle to cover over half the thickness resulted in a nice result, easier that the other solution, faster, but still much harder than idea...
But, as long as you want the circle to be black... I have found the easiest answer!!!
Just click on the paint brush tool, and make the paint brush size the size you want circle, it draws a perfect 1 pixel width circle! You just need to take a screen shot of the circle (hit print screen), paste it into a new image, and retrieve your circle!
Actually, another way that I just realized is that you can just use the brush to draw a solid circle, then without moving your pointer, reduce the brush size twice and press to paint with the right click or background colour... If you are doing this in a multiply layer this won't even wipe out stuff on other layers and the white won't be seen...