Thank you for the quick response Ego Eram Reputo. I thought this might be the case as after many google searches I was coming up empty.
I can tell you, there are other options such as photoshop that will allow you to do this. Perhaps it would be a good project for someone brighter than me when it comes to modifications for paint.net
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I have been using Paint.Net for about 6 months now, and I found creating photos is quite fun and have learned a great deal!
This input was very helpful though. Are you able to recommend any free HTML editors that could help me with this project?