Thank you. While the D&A is indeed useful, sadly it doesn't solve my problem. As I mentioned in my original post, What I have is an actual LIVE bottle. What I really wanted to do is to trace an outline of a label that will conform to it's shape; from there, I will then enter the texts and images.
Aside from PaintDotNet, I also have Corel X5. I am really a newbie with both applications. Again, thank you.