When I attempt to access Paint.Net's Web site, Firefox v70.0.1 blocks access by default, complaining that it doesn't recognize Comodo as a certificate issuer, of course it should accept Comodo's certificates unless there's been a recent security breach of Comodo that I don't know about. See the attached screengrab.
I'll be reporting this to Comodo (I use their Windows Internet Security product) and Mozilla, but it probably would be a good idea if the getpaint.net admins reported the problem, too.