Weird, I just confirmed this. It seems to happen with many RGB values not just 255, though certain values do not change when you use the eyedropper. I can only assume that PdN stores colors in a different format than ARGB so some rounding occurs when you actually draw on the image. So I don't think that the eyedropper is picking up the "wrong" color, rather the color you're actually drawing is slightly different from the one you selected. So this bug shouldn't actually affect your drawings in any way as the visual difference between 254 and 255, for example, is essentially nothing.